A number of factors determine the severity of damage caused by a volcano or an earthquake:
The type of plate boundary that has caused the volcano - destructive plate boundaries cause violent volcanoes.
The proximity of a volcano or an earthquake's epicentre to a large settlement - those situated near large cities where population is dense cause more deaths than those in less populated areas.
The proximity of an earthquake's focus to the earth's surface - the closer the focus the more powerful the earthquake.
The wealth of the country in which it erupts - a developed country can afford scientific prediction instruments, buildings that are designed to withstand earthquakes, a quick reaction force and good medical care for the injured.
The time of day when the earthquake strikes - if it strikes when people are congregated in one area, for example, at rush hour, its results can be more devastating.
To answer the question 'why are some countries at greater risk from tectonic hazards than others' you are going to compare two case studies.